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Some Effective Methods for Treatment of Wastewater from Cu Production

  • Vesna KrstićEmail author
Chapter
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Part of the Environmental Chemistry for a Sustainable World book series (ECSW, volume 53)

Abstract

The total global production of refined copper in 2017 was approximately 19 million tons, with an annual growth rate of 3.4%. During the copper production process, a large proportion of the accompanying toxic metals end up in the environment. For this reason, there is a significant need for advanced wastewater treatment methods and technologies in order to ensure optimal water quality, eliminate heavy metals and other pollutants from water, and suggest appropriate industrial technology for the treatment of wastewater. Although various techniques for treatment of wastewater contaminated with heavy metals are being applied today, the choice of the most suitable wastewater treatment process depends on some basic commonly accepted parameters which will be discussed in this paper.

The methods and techniques such as adsorption on the new sorbents (biosorbents, agricultural and industrial wastes (lignocellulosic materials) as an ecological adsorbent; nano-adsorbents, activated carbon, carbon nanotubes, graphene, MgO, MnO, ZnO, TiO2, Fe3O4, etc.), nanotechnology, photocatalysis, nano zero-valent iron (nZVI), the use of dimensionally stable anodes in electrolysis, and phytoremediation have proved to be adequate in the treatment of wastewater from the support in particular toxic metals such as copper (Cu), lead (Pb), cadmium (Cd), nickel (Ni), chromium (Cr), arsenic (As), zinc (Zn), and mercury (Hg), from primary and secondary copper production. Sorbents can be regenerated or concentrated by combustion and electrolysis using dimensionally stable anode; metals can be selectively separated and can be returned to the production process. Working principles and the advantages and disadvantages of the mentioned materials and methods for water remediation will be discussed in this paper. Due to their importance of the impact on the living world and on the environment, the toxicity of each of these polluting metals will also be demonstrated. The results show that water is generally polluted and that in the near future, we will have to take the most serious approach to addressing this problem. Great efforts are already being made to come up with the most efficient and inexpensive methods for wastewater treatment. This generally requires combining multiple methods for quality problem-solving, in accordance with the type and concentration of the pollution identified. In addition to engaging experts from the natural sciences, it is also necessary to include a management system and link up ministries of ecology at the state level and international level, in order to approach this problem more efficiently and to preserve rivers that flow through multiple lands and carry with them substances harmful to human health and to the environment and rivers which then flow with these substances into lakes, seas, and oceans.

Keywords

Toxicity and heavy metals Wastewater treatment Adsorption on new adsorbents Nanotechnology Photocatalysis Nano zero-valent iron Dimensionally stable anode Phytoremediation 

Abbreviations

ANFIS

Adaptive neural fuzzy inference system

BDST

Bed depth service time

BE

Binding energy

BET

Brunauer–Emmett–Teller

CNMs

Carbon nanomaterials

CS/SCNTs

Chitosan/silicon-coated carbon nanotubes

DSA

Dimensionally stable anode

DSE

Dimensionally stable electrodes

DLVO

Derjaguin, Landau, Verwey, and Overbeek theory

EDTA

Ethylenediaminetetraacetic acid

EDX

Energy-dispersive X-ray

ENMs

Electrospun nanofiber membranes

EU

European Union

FRAP

Ferric reducing antioxidant power

FTIR

Fourier transform infrared spectroscopy

GO

Graphene oxide

HRAES

High-resolution Auger electron spectroscopy

IET

Isoelectric point

MC

Mesoporous carbon

MCL

Maximum contaminant level

MMO

Mixed metal oxide

MSC

Modified mesoporous silica–carbon

MWCNTs

Multiwalled carbon nanotubes

NA

Not available

NF

Nanofiltration

NMR

Nuclear magnetic resonance

NPs

Nanoparticles

nZVI

Nano zero-valent iron

NT

Nanotube

OEP

Oxygen evolution potential

OER

Oxygen evolution reaction

PBI

Polybenzimidazole

PES

Polyethersulfone

PET

Polyethylene terephthalate

ppb

Parts-per-billion

PGMs

Platinum group metals

PPTA

Para-phenylene terephthamide

PS

Polystyrene

PSF

Polysulfone

PVC

Polyvinyl chloride

PVDF

Polyvinylidene fluoride

PVP

Polyvinylphenol

RO

Reverse osmosis

SEM

Scanning electron microscopy

SHE

Standard hydrogen electrode

SWCNTs

Single-walled carbon nanotubes

TEM

Transmission electron microscopy

TGA

Thermogravimetric analysis

UF

Ultrafiltration

US EPA

United States Environmental Protection Agency

UV

Ultraviolet

WHO

World Health Organization

XPS

X-ray photoelectron spectroscopy

XRD

X-ray diffraction

Notes

Acknowledgments

This review was supported by the Ministry of Education and Science of the Republic of Serbia. The author expresses great gratitude to the Ministry for Agreement No 451-03-68/2020-14/200052. The author is also thankful to Professor Carmen Blanco Delgado and especially to Professor Nicola Bolton, Marjan Gorišek and Jim Fleming for their overall support and selfless assistance. Also, the author is thankful to my loved ones for their patience and understanding.

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© The Editor(s) (if applicable) and The Author(s), under exclusive license to Springer Nature Switzerland AG 2021

Authors and Affiliations

  1. 1.Mining and Metallurgy Institute BorBorRepublic of Serbia
  2. 2.Technical FacultyUniversity of BelgradeBorRepublic of Serbia

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