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Structure, Reactivity, and Selectivity of Metal-Peroxo Complexes Versus Dioxiranes

  • Waldemar Adam
  • Catherine M. Mitchell
  • Chantu R. Saha-Möller
  • Oliver Weichold
Chapter
Part of the Structure and Bonding book series (STRUCTURE, volume 97)

Abstract

Dioxiranes, MTO/H2O2, and MTO/UHP are becoming increasingly important as efficient and selective oxidants in organic chemistry and numerous publications have appeared on each of them. Here we present a comprehensive review, comparing the chemistry of these reagents with particular emphasis on the oxidation of π bonds, heteroatoms, and σ bonds. We will discuss structural aspects and on this basis, will outline the reactivity and selectivity of these oxidants, along with the mechanistic aspects of the oxygen-transfer process.

Keywords

Peroxo complexes Dioxiranes Oxygen transfer Reactivity Chemoselectivity Regioselectivity Diastereoselectivity Enantioselectivity 

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Copyright information

© Springer Verlag Berlin Heidelberg 2000

Authors and Affiliations

  • Waldemar Adam
    • 1
  • Catherine M. Mitchell
    • 1
  • Chantu R. Saha-Möller
    • 1
  • Oliver Weichold
    • 1
  1. 1.Institut für Organische Chemie der Universität WürzburgWürzburgGermany

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