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Lambda Transitions in Minerals

  • A. B. Thompson
  • E. H. Perkins
Chapter
Part of the Advances in Physical Geochemistry book series (PHYSICAL GEOCHE, volume 1)

Abstract

Despite the vast increase in the collection and use of thermochemical and crystallographic data in recent years, understanding of phase transitions in minerals has not advanced as much as has understanding of the transformations in other inorganic crystals or fluids. The limitations result partly from the relatively sluggish transformation kinetics of the complex structure of rock-forming minerals, partly from the relatively crude experimental techniques used in most mineralogical studies and partly from an unawareness of developments in other branches of physical sciences, especially the theoretical developments since the classical thermodynamic work of Gibbs. We have made a crude attempt to follow developments associated with the various transitions in many different chemical systems and thermodynamic reference frames and present aspects from the more comprehensive works on phase transitions. We hope that they may find wider application in mineralogy and petrology. Because of lack of space, we refer often to the review articles rather than original sources. To avoid confusion with established conventions, we use the terms transformation, transition, and inversion synonomously.

Keywords

Differential Scanning Calorimetry Heat Capacity Tricritical Point Antiferromagnetic Transition Displacive Transformation 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer-Verlag New York Inc 1981

Authors and Affiliations

  • A. B. Thompson
  • E. H. Perkins
    • 1
  1. 1.Dept. of Geological SciencesUniversity of British ColumbiaVancouverCanada

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