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That Fascinating Nonclassical Ion Problem

  • Herbert C. Brown
Chapter
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Abstract

In science it is rare that a concept, once it has been fully accepted and incorporated into both current theory and textbooks, is successfully challenged. For fifteen years the author and his students have been engaged in a research program directed to testing the validity of the proposal that σ-bridges play a major role in the structures and chemistry of the 2-norbornyl1 and the cyclopropylcarbinyl2 cations, as well as numerous other σ-bridged, so-called “nonclassical ions.”3

Keywords

Steric Strain Carbonyl Cluster Boron Hydride Multicenter Bonding Secondary Isotope Effect 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Press, New York 1977

Authors and Affiliations

  • Herbert C. Brown
    • 1
  1. 1.Purdue UniversityWest LafayatteUSA

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