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Substituent and Structural Effects in 2-Norbornyl

  • Herbert C. Brown
Chapter
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Abstract

The data for the stabilized 2-p-anisyl-2-norbornyl and related tertiary derivatives (Chapter 7) reveal high exo : endo rate and product ratios comparable to those revealed by the parent secondary system, 2-norbornyl itself. This is made evident by a comparison of the Goering-Schewene diagram for the solvolysis of 1,2-dimethyl-2-norbornyl p-nitrobenzoate (Figure 11.1) with that for 2-norbornyl acetate (Figure 11.2).

Keywords

Structural Effect Charge Delocalization Endo Isomer Representative Solvent Secondary Derivative 
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Copyright information

© Plenum Press, New York 1977

Authors and Affiliations

  • Herbert C. Brown
    • 1
  1. 1.Purdue UniversityWest LafayatteUSA

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