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Capture of Unsymmetrical 2-Norbornyl Cations

  • Herbert C. Brown
Chapter

Abstract

The direct tests with appropriate substituents for charge delocalization from the 2-1 to the 1-2 and 6-3,4 positions in solvolytic reactions of 2-norbornyl derivatives all failed to confirm such charge delocalization (Chapter 11). It was then suggested that “there are good reasons to expect carbon bridging to lag behind C-X ionization at the transition state.”5

Keywords

Hydrogen Chloride Full Equilibration Resonance Hybrid Cyclic Addition Molecular Addition 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Press, New York 1977

Authors and Affiliations

  • Herbert C. Brown
    • 1
  1. 1.Purdue UniversityWest LafayatteUSA

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