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Stabilized 2-Norbornyl Cations

  • Herbert C. Brown
Chapter
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Abstract

The position that the importance of neighboring group participation should diminish as an incipient cationic center is stabilized by substitution1 appears to be generally accepted.2 Consequently, we undertook to synthesize representative 2-norbornyl systems containing a stabilizing p-anisyl group at the 2-position in order to establish its effect on the exo :endo rate and product ratios.

Keywords

Product Ratio Endo Isomer Free Energy Diagram Dimethyl Ketal Secondary Derivative 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Press, New York 1977

Authors and Affiliations

  • Herbert C. Brown
    • 1
  1. 1.Purdue UniversityWest LafayatteUSA

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