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Potentiometric and Spectroscopic Studies on the Ternary Complexes of Copper(II) and Palladium(II) with Peptides and Nucleobases

  • I. Sóvágó
  • A. Kiss
  • E. Farkas
  • B. Lippert
Chapter
  • 259 Downloads
Part of the NATO ASI Series book series (ASEN2, volume 26)

Abstract

The binary complexes of transition metal ions with dipeptides or nucleobases have already been well-characterized and the most important findings were rewieved by several authors [1, 2]. In case of oligopeptides the metal binding ability of the ligands depends on the the involvement of amide nitrogens and side chain residues in metal ion coordination. Copper(II) and palladium(II) were reported to be the most effective to induce deprotonation and coordination of amide nitrogens and, as a consequence, these metal ions form especially stable complexes with dipeptides.

Keywords

Stability Constant Ternary Complex Binary Complex Nitrogen Donor Stability Order 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer Science+Business Media Dordrecht 1997

Authors and Affiliations

  • I. Sóvágó
    • 1
  • A. Kiss
    • 1
  • E. Farkas
    • 1
  • B. Lippert
    • 2
  1. 1.Department of Inorganic and Analytical ChemistryL. Kossuth UniversityDebrecenHungary
  2. 2.Fachbereich ChemieUniversität DortmundDortmundGermany

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